| 高温高压条件下泥质岩变质脱水作用的实验研究 |
其他题名 | Experimental Study on Dehydration of pelites under High-Pressure and High-Temperature
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| 李营
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| 2006-12-26
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学位授予单位 | 中国科学院地球化学研究所
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学位授予地点 | 地球化学研究所
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学位名称 | 博士
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关键词 | 泥质岩
沉积物
俯冲带
俯冲带流体
高温高压
热力学计算
变质脱水作用
微量元素
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摘要 | 泥质岩是地球上广泛分布的一种表壳沉积岩石,与上地壳平均化学组成接近,是俯冲带沉积物的典型代表。本文以赣北双桥山群泥质板岩为主要研究对象,对泥质岩(KFMASH体系)进行了热力学计算、高压差热(HP-DTA)和榴辉岩相温压条件下变质脱水作用的实验研究。研究结果表明,俯冲沉积物在冷、热俯冲带其变质脱水作用的深度范围分别是95~155 km 和48~84 km。泥质岩经历了一个区域进变质作用过程。该过程可以被分为三个阶段:① 绿泥石变质脱水阶段;② 角闪石、白云母变质脱水阶段;③ 黑云母变质脱水阶段。在各阶段中,随含水矿物的变质脱水作用不断进行,流体被逐渐从体系中释放出来。最后以黑云母的消失为标志,指示了泥质岩体系变质脱水作用的结束。在俯冲带深部温度压力条件下,泥质岩所释放出的流体以富集Cu、Pb、Nd、Ba等流体活动性元素为主要特征。俯冲带沉积物(岩)在进入到俯冲带深部前,受海水浸染而富集Cl,这导致其在俯冲带深部变质脱水过程中,所释放出的流体中富集Cu、Pb、Rb、Sr、Cs、La、Ba、Ce、Pr、Nd、Sm、Eu等微量元素。而未受到海水浸染或浸染程度较弱俯冲带沉积物,在俯冲带变质脱水过程中所释放出的变质流体中,上述微量元素的富集程度则相对较弱。 |
其他摘要 | Pelite is a typical representation of subducted sediments, as it is widely distributed in the crust and has similar chemical composition to the upper crust. Here we report the results from thermodynamic calculation and high-pressure experimental investigation on natural pelites. Experimental methods include high-pressure differential thermal analysis (HP-DTA) and experiments under constant pressure and temperature.Our results suggest that the dehydrations of subducted sediments in cold and hot subduction zones will take place in different depths, ranging from 95 to 155 km and from 48 to 84 km respectively. Three major dehydration stages are determined by the consuming of different hydrous minerals during the metamorphic dehydration of pelites: (1) chlorite dehydration, (2) amphibole-muscovite dehydration, and (3) biotite dehydration. The dehydration of subducted sediments ceases as the vanish of biotite.Under the P-T conditions in deep subduction zones, the fluid released from subducted sediments is enriched in fluid-mobile elements such as Cu, Pb, Nd, and Ba. In addition, our results show that the fluid released from the sediments with certain amounts of chloride due to possible contact with seawater has higher contents of some trace elements including Cu, Pb, Rb, Sr, Cs, La, Ba, Ce, Pr, Nd, Sm and, Eu, than that liberated from the sediments being not or lightly disseminated by seawater. |
页数 | 80
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语种 | 中文
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文献类型 | 学位论文
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条目标识符 | http://ir.gyig.ac.cn/handle/352002/3176
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专题 | 研究生_研究生_学位论文
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推荐引用方式 GB/T 7714 |
李营. 高温高压条件下泥质岩变质脱水作用的实验研究[D]. 地球化学研究所. 中国科学院地球化学研究所,2006.
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