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清镇(EH3)和某些其它顽火辉石球粒陨石硫化物的微量元素及其成因意义
陈永亨
1990
学位授予单位中国科学院地球化学研究所
学位授予地点中国科学院地球化学研究所
学位名称博士
摘要顽火辉石球粒陨石群是一个具有异常化学和矿物组成的小群,由于它们形成于异常的母体环境而表现出许多明显不同于其它球粒陨石群的特殊性质,例如对它们的母体物质来源、形成区域、氧化还原条件、吸积温度、变质作用及母体群数目、球粒陨石和无球粒陨石之间的成因联系等等,一直争论不休。非平衡的清镇顽火辉石球粒陨石(EH3)具有复杂的硫化物集合体,保存了早期星云过程的结构和化学特征,为了分析这些相中作为指示剂元素的某些微量元素丰度,我们经过反复实验建立了一套从光片上分离单矿物颗粒,并对μg级单矿物样品进行INAA测定的方法。运用该方法和电子探针分析研究了清镇及一些顽火辉石球粒陨石中陨硫钙石、硫镁矿、硫锰矿、硫铜钾矿、陨硫铁和A、B矿的矿物化学组成和微量元素丰度。综合清镇顽火辉石球粒陨石及某些顽火辉石球粒陨石、无球粒陨石的岩石矿物学、矿物化学、全岩化学组成、年代学和同位素组成以及硫化物微量元素丰度的研究结果,论证了顽火辉石球粒陨石的母体物质来源于太阳组成气体星云,距离太阳≤0.7AU,具有富H和富C特征,表观效应C/O≥1,星云压力为10~(-2)-10~(-4)大气压,母体吸积温度为600-700K,热变质作用导致硫化物中微量元素发生重新分配,EH和EL为两个不同的母体群,经历岩浆分异作用产生各自对应的顽火辉石无球粒陨石,从而建立了清镇及顽火辉石球粒陨石母体形成演化的大致轮廓。
其他摘要The enstatite chondrites are a small group with unusual chemical and mineralogical compositions. As they were formed in a unique reducing enviroment, they exhibit a number of unique properities that are significantly different from those of carbonaceous and ordinary chondrites. For example, the material sources of the parent body, formation location, redox enviroment, accretion temperature of the parent body, metamorphism and number of the parent bodies, the genetic connection between enstatite chondrites and aubrites are still of great debate. In order to determine trace element abundances as indicative elements in complex sulfide assembleges of the most unequilibrated enstatite chondrites-Qingzhen (EH3), which preserves the texture and chemical imprint of early solar nebular processes, we have established the methods of separating mineral grains from polished sections of meteorites and analyzed them by INAA on the basis of repeated experiments. The chemical compositions and trace element abundances of oldhamite, niningerite, alabandite, djerfisherite, troilite and minerals A, B and Qingzhen and some other enstatite chondrites have been determined by electron microprobe and INAA. To sum up, the research results of Qingzhen and some other enstatite chondrites as well as aubrites with respect to their petrologic mineralogy, mineralogical chemistry, bulk chemistry, chronology and isotopic composition as well as trace element abundances of sulfides provide evidence suggesting that parent materials of enstatite chondrites came from the nebulae of solar composition, the formation location is ≤0.7AU far from the sun, the nebula is enriched in H and C so that the apparent effect is similar to one of C/O ≥ 1, nebular pressure is 10~(-2)-10~(-4) atm., accretion temperature of the parent bodies is 600-700K, the trace elements in sulfides were re-ditributed during metamorphism, EH and EL chondrites were derived from different parent bodies, aubrites are of magmatic differentiation origin. We have outlined the general picture of the formation and evolution of Qingzhen enstatite chondrite and its parent body on the basis of the above results.
页数113
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/3818
专题研究生_研究生_学位论文
推荐引用方式
GB/T 7714
陈永亨. 清镇(EH3)和某些其它顽火辉石球粒陨石硫化物的微量元素及其成因意义[D]. 中国科学院地球化学研究所. 中国科学院地球化学研究所,1990.
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