Chalcophile elemental compositions and origin of the Tuwu porphyry Cu deposit, NW China

	Chalcophile elemental compositions and origin of the Tuwu porphyry Cu deposit, NW China
	Jian-Feng Gao; Mei-Fu Zhou; Liang Qi; Wei Terry Chen; Xiao-wen Huang
	2015
发表期刊	Ore Geology Reviews
卷号	66 403-421 期号:1 页码:403-421
摘要	The Tuwu porphyry Cu deposit in the eastern Tianshan Orogenic Belt of southern Central Oceanic Orogen Belt contains 557 Mt ores at an average grade of 0.58 wt.% Cu and 0.2 g/t Au, being the largest porphyry Cu deposit in NW China. The deposit is genetically related to dioritic and plagiogranitic porphyries that intruded the Carboniferous Qieshan Group. Ore minerals are dominantly chalcopyrite, pyrite and enargite. Porphyric diorites have Sr/ Y and La/Yb-N ratios lower but Y and Yb contents higher than plagiogranites. Diorites have highly variable Cu but nearly constant PGE contents (most Pd = 0.50-1.98 ppb) with Cu/Pd ratios ranging from 10,900 to 8,900,000. Plagiogranites have PGEs that are positively correlated with Cu and have nearly uniform Cu/Pd ratios (5,100,000 to 7,800,000). Diorites have concentrations of Re (0.73-15.18 ppb), and Re-187/Os-188 and Os-187/Os-188 ratios lower but common Os contents (0.006-0.097 ppb) higher than plagiogranites. However, both the diorites and plagiogranites have similar normalized patterns of rare earth elements (REE), trace element and platinum-group elements (PGEs). All the samples are characterized by the enrichments of LREE relative to HREE and display positive anomalies of Pb and Sr but negative anomalies of Nb and Ta in primitive-mantle normalized patterns. In the primitive mantle-normalized siderophile element diagrams, they are similarly depleted in all PGEs but slightly enriched in Au relative to Cu. Our new dataset suggests that both the diorite and plagiogranite porphyries were likely evolved from magmas derived from partial melting of a wet mantle wedge. Their parental magmas may have had different water contents and redox states, possibly due to different retaining time in staging magma chambers at the depth, and thus different histories of magma differentiation. Parental magmas of the diorite porphyries are relatively reduced with less water contents so that they have experienced sulfide saturation before fractional crystallization of silicate minerals, whereas the relatively more oxidized parental magmas with higher water contents of the plagiogranite porphyries did not reach sulfide saturation until the magmatic-hydrothermal stage. Our PGE data also indicates that the Cu mineralization in the Tuwu deposit involved an early stage with the enrichments of Au, Mo and Re and a late stage with the enrichment of As but depletion of Au-Mo. After the formation of the Cu mineralization, meteoric water heated by magmas penetrated into and interacted with porphyritic rocks at Tuwu, which was responsible for leaching Re from hosting rocks.
学科领域	矿床地球化学
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.gyig.ac.cn/handle/352002/5996
专题	矿床地球化学国家重点实验室_矿床地球化学国家重点实验室_期刊论文矿床地球化学国家重点实验室
推荐引用方式 GB/T 7714	Jian-Feng Gao,Mei-Fu Zhou,Liang Qi,et al. Chalcophile elemental compositions and origin of the Tuwu porphyry Cu deposit, NW China[J]. Ore Geology Reviews,2015,66 403-421(1):403-421.
APA	Jian-Feng Gao,Mei-Fu Zhou,Liang Qi,Wei Terry Chen,&Xiao-wen Huang.(2015).Chalcophile elemental compositions and origin of the Tuwu porphyry Cu deposit, NW China.Ore Geology Reviews,66 403-421(1),403-421.
MLA	Jian-Feng Gao,et al."Chalcophile elemental compositions and origin of the Tuwu porphyry Cu deposit, NW China".Ore Geology Reviews 66 403-421.1(2015):403-421.

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