矿床地球化学国家重点实验室知识库

A common perception is that oxidized magma is critical for the formation of a porphyry Cu ± Mo ± Au ore deposit. We have used an ore-bearing pluton (Tongchang) and an ore-barren pluton (Shilicun) in the western rim of the South China block to test this idea and to determine other important controls on ore genesis. Zircon UPb ages indicate that the Tongchang and Shilicun plutons were emplaced at 36.3 ± 0.2 Ma and 35.2 ± 0.4 Ma, respectively, broadly coinciding with strike-slip faulting in the region and continental collision that occurred ~300 km to the west. These two plutons are all characterized by significant light REE enrichments and pronounced negative NbTa anomalies, similar to the bulk crust. Apatite separates from these two plutons all have elevated initial ⁸⁷Sr/⁸⁶Sr (Tongchang, 0.70690 to 0.70796; Shilicun, 0.70703 to 0.70726) and negative ε_Nd(t) (Tongchang, −6.2 to −7.3; Shilicun, −4.5 to −5.8). The mean ε_Hf(t) and δ¹⁸O of zircon from these plutons are −1.4 and 6.8‰ for Tongchang, and −0.3 and 6.5‰ for Shilicun. The Sr-Nd-Hf isotope compositions are all within the ranges of the Neoproterozoic mafic arc lower crust in the region. Whole-rock U-Nb-Ta systematics indicate that the Tongchang and Shilicun plutons originated from an amphibole-bearing source and a garnet-bearing source, respectively, implying a shallower and more H₂O-rich mafic source for the former than the latter. Quartz trace element data indicate that the Tongchang pluton was emplaced at a shallower depth than the Shilicun pluton. Zircon Ce⁴⁺/Ce³⁺ and whole-rock V/Sc ratios, and apatite SO₃ and MnO contents indicate that the parental magmas of both plutons are as oxidized as those of some porphyry Cu deposits in northern Chile, but the parental magma of the Tongchang pluton is less oxidized than that of the Shilicun pluton. Apatite Cl-F-OH systematics and higher abundant hydrous silicate minerals such as amphibole and biotite in the Tongchang pluton than the Shilicun pluton indicate that the parental magma of the Tongchang pluton has higher Cl and H₂O content than that of the Shilicun pluton. Our results show that oxidized magma is important but this alone cannot make a porphyry Cu ± Mo ± Au ore deposit. High contents of H₂O-Cl in magma and shallow depth of emplacement are also important.